Chloroiodomethane
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| Stereo, skeletal formula of chloroiodomethane with all explicit hydrogens added | |
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| Names | |
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| Preferred IUPAC name
Chloroiodomethane[citation needed]
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| Systematic IUPAC name
Chloro(iodo)methane[1]
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Other names
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| Identifiers | |
593-71-5  |
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| 1730802 | |
| ChemSpider | 11154 |
| EC Number | 209-804-8 |
| Jmol 3D model | Interactive image |
| PubChem | 11644 |
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| Properties | |
| CH2ClI | |
| Molar mass | 176.38 g·mol−1 |
| Appearance | Colorless liquid |
| Density | 2.422 g mL−1 |
| Boiling point | 108 to 109 °C (226 to 228 °F; 381 to 382 K) |
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Henry's law
constant (kH) |
8.9 μmol Pa−1 kg−1 |
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Refractive index (nD)
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1.582 |
| Vapor pressure | {{{value}}} |
| Related compounds | |
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Related alkanes
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Related compounds
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2-Chloroethanol |
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Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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 verify (what is  ?) |
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| Infobox references | |
Chloroiodomethane is a mixed liquid halomethane very soluble in acetone, benzene, diethyl ether and alcohol. Its refractive index is 1.5812 - 1.5832.
It crystallizes orthorhombic crystal system with space group Pnma with lattice constants: a = 6.383, b = 6.706, c = 8.867 (.10−1 nm).[2]
Chloroiodomethane is used in cyclopropanation (Simmon-Smith reaction), Mannich reaction, aminomethylation, epoxidation, ring opening and addition to terminal alkenes. It often replaces diiodomethane because of higher yields and selectivity.
References
External links
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