1,5-Hexadiene

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1,5-Hexadiene
!,5-hexadienestick.png
Names
Other names
diallyl, biallyl
Identifiers
592-42-7
Jmol 3D model Interactive image
PubChem 11598
  • C=CCCC=C
Properties
C6H10
Molar mass 82.15 g·mol−1
Appearance colorless liquid
Boiling point 59–60 °C (138–140 °F; 332–333 K)
Vapor pressure {{{value}}}
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

1,5-Hexadiene is the organic compound with the formula (CH2)2(CH=CH2)2. It is a colorless, volatile liquid. It is used as a crosslinking agent and precursor to a variety of other compounds.

Synthesis

1,5-Hexadiene is produced commercially by the ethenolysis 1,5-cyclooctadiene:[1]

(CH2CH=CHCH2)2 + 2 CH2=CH2 → 2 (CH2)2(CH=CH2

The catalyst is derived from Re2O7 on alumina

A laboratory-scale preparation involves reductive coupling of allyl chloride using magnesium:[2]

2 ClCH2CH=CH2 + Mg → (CH2)2(CH=CH2)2 + MgCl2

References

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