Sodium perrhenate

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Sodium perrhenate
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Identifiers
13472-33-8 YesY
ChEMBL ChEMBL444819 N
Jmol 3D model Interactive image
PubChem 5107658
RTECS number WD3675000
  • InChI=1S/Na.4O.Re/q+1;;;;-1;
  • [O-][Re](=O)(=O)=O.[Na+]
Properties
NaReO4
Molar mass 273.194 g/mol
Appearance White crystalline powder
Density 5.39 g/cm3
Melting point 414 °C (777 °F; 687 K)
103.3 g/100 mL (0 °C)
145.3 g/100 mL (30 °C)
173.0 g/100 mL (50 °C)
Solubility soluble in ethanol
Structure
tetragonal
Vapor pressure {{{value}}}
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YesYN ?)
Infobox references

Sodium perrhenate (also known as Sodium Rhenate(VII)) is the inorganic compound with the formula NaReO4 It is a white crystalline solid that is soluble in water. It is a common precursor to rhenium compounds. Its structure resembles that of sodium perchlorate and sodium permanganate.

Preparation

It can be prepared by treatment of rhenium heptoxide with base or by ion exchange from the potassium salt.

Reactions

It reacts with sodium in ethanol to give nonahydridorhenate.[1] and with polysulfide solutions to give tetrathiorhenate. [2]

References

  1. A. P. Ginsberg, C. R. Sprinkle, Nonahydridorhenate Salts" Inorganic Syntheses 1972, vol. 13, pp. 219–225. doi: 10.1002/9780470132449.ch45
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Further reading

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