Zirconium nitride
Zirconium nitride in the unit cell | |
Names | |
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IUPAC name
Zirconium nitride
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Other names
Zirconium(III) nitride, Nitridozirconium
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Identifiers | |
25658-42-8 | |
ChemSpider | 85159 |
EC Number | 247-166-2 |
Jmol 3D model | (Zr≡N): Interactive image |
PubChem | 94359 |
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Properties | |
ZrN[1] | |
Appearance | Yellow-brown crystals |
Odor | Odorless |
Density | 7.09 g/cm3 (24 °C)[1] |
Melting point | 2,952 °C (5,346 °F; 3,225 K) at 760 mmHg[1] |
Insoluble | |
Solubility | Soluble in concentrated HF, acids[1] |
Structure | |
Cubic, cF8[2] | |
Fm3m, No. 225[2] | |
a = 4.5675 Å[2]
α = 90°, β = 90°, γ = 90°
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Octahedral[2] | |
Thermochemistry | |
40.442 J/mol·K[3] | |
Std molar
entropy (S |
38.83 J/mol·K[3] |
Std enthalpy of
formation (ΔfH |
−365.26 kJ/mol[3] |
Related compounds | |
Related refractory ceramic materials
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Tantalum carbide Niobium carbide Zirconium carbide |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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verify (what is ?) | |
Infobox references | |
Zirconium nitride (ZrN) is an inorganic compound used in a variety of ways due to its properties.
Properties
ZrN grown by physical vapor deposition (PVD) is a light gold color similar to elemental gold. ZrN has a room-temperature electrical resistivity of 12.0 µΩ·cm, a temperature coefficient of resistivity of 5.6·10−8 Ω·cm/K, a superconducting transition temperature of 10.4 K, and a relaxed lattice parameter of 0.4575 nm. The hardness of single-crystal ZrN is 22.7±1.7 GPa and elastic modulus is 450 GPa.[4]
Uses
Zirconium nitride is a hard ceramic material similar to titanium nitride and is a cement-like refractory material. Thus it is used in refractories, cermets and laboratory crucibles. When applied using the physical vapor deposition coating process it is commonly used for coating medical devices,[5] industrial parts (notably drill bits), automotive and aerospace components and other parts subject to high wear and corrosive environments.[6]
Also zirconium nitride was suggested as a hydrogen peroxide fuel tank liner for rockets and aircraft.[7]
References
- ↑ 1.0 1.1 1.2 1.3 Lua error in package.lua at line 80: module 'strict' not found.
- ↑ 2.0 2.1 2.2 2.3 Lua error in package.lua at line 80: module 'strict' not found.
- ↑ 3.0 3.1 3.2 Zirconium nitride in Linstrom, P.J.; Mallard, W.G. (eds.) NIST Chemistry WebBook, NIST Standard Reference Database Number 69. National Institute of Standards and Technology, Gaithersburg MD. http://webbook.nist.gov (retrieved 2014-06-30)
- ↑ Lua error in package.lua at line 80: module 'strict' not found.
- ↑ Lua error in package.lua at line 80: module 'strict' not found.
- ↑ Lua error in package.lua at line 80: module 'strict' not found.
- ↑ 7736751
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