Tetranitratoborate

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Tetranitratoborate is an anion composed of boron with four nitrate groups. It has formula [B(NO3)4]. It can form salts with large cations such as tetramethyl ammonium nitratoborate,[1] or tetraethyl ammonium tetranitratoborate.[2]

The ion was first discovered by C. R. Guibert, M. D. Marshall in 1966 after failed attempts to make boron nitrate.[1]

The related molecule, boron nitrate B(NO3)3, has resisted attempts to make it, and if it exists it is unstable above -78 °C.[2]

Other related ions are the slightly more stable tetraperchloratoborates, with perchlorate groups instead of nitrate, and tetranitratoaluminate[3] with the next atom down the periodic table, aluminium instead of boron ([Al(NO3)4]).

Formation

Tetramethyl ammonium chloride reacts with BCl3 to make (CH3)4NBCl4. Then the tetrachloroborate is reacted with N2O4 at around -20° to form tetramethyl ammonium nitratoborate, and other gases such as NO2Cl and Cl2.[2]

Another mechanism to make tetranitratoborate salts is to shake a metal nitrate with BCl3 in chloroform at 20 °C for several days. Chloronitratoborate [Cl3BNO3] is an unstable intermediate.

MNO3 + BCl3 M[Cl3BNO3]
4M[Cl3BNO3] 3M[BCl4] + MB(NO3)4][4]

Properties

The infrared spectrum of tetramethyl ammonium nitratoborate includes a prominent line at 1612 cm−1 with shoulders at 1582 and 1626 cm−1 attributed to v4. Also prominent is 1297 and 1311 cm−1 attributed to v1, with these vibrations due to the nitrate bonded via one oxygen.[1]

The density of tetramethyl ammonium nitratoborate is 1.555. It is colourless and crystalline. As tetramethyl ammonium nitratoborate is heated it has some sort of transition between 51 °C and 62°. It decomposes above 75 °C producing gas. Above 112° it is exothermic, and a solid is left if it is heated to 160 °C.[2]

Tetramethyl ammonium nitratoborate is insoluble in cold water but slightly soluble in hot water. It does not react with water. It also dissolves in liquid ammonia, acetonitrile, methanol, and dimethylformamide.[1] It reacts with liquid sulfur dioxide.[1][5]

At room temperature tetramethyl ammonium nitratoborate is stable for months. It does not explode with impact.[1]

Alkali metal tetranitratoborates are unstable at room temperature and decompose.[4]

1-Ethyl-3-methyl-imidazolimium tetranitratoborate was discovered in 2002. It is an ionic liquid that turns solid at -25 °C.[6]

References

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Salts and covalent derivatives of the Nitrate ion
HNO3 He
LiNO3 Be(NO3)2 B(NO3)4 C N O FNO3 Ne
NaNO3 Mg(NO3)2 Al(NO3)3 Si P S ClONO2 Ar
KNO3 Ca(NO3)2 Sc(NO3)3 Ti(NO3)4 VO(NO3)3 Cr(NO3)3 Mn(NO3)2 Fe(NO3)3 Co(NO3)2,
Co(NO3)3
Ni(NO3)2 Cu(NO3)2 Zn(NO3)2 Ga(NO3)3 Ge As Se Br Kr
RbNO3 Sr(NO3)2 Y Zr(NO3)4 Nb Mo Tc Ru Rh Pd(NO3)2 AgNO3 Cd(NO3)2 In Sn Sb Te I Xe(NO3)2
CsNO3 Ba(NO3)2   Hf Ta W Re Os Ir Pt Au Hg2(NO3)2,
Hg(NO3)2
Tl(NO3)3 Pb(NO3)2 Bi(NO3)3 Po At Rn
Fr Ra   Rf Db Sg Bh Hs Mt Ds Rg Cn Uut Fl Uup Lv Uus Uuo
La Ce(NO3)3,
Ce(NO3)4
Pr Nd Pm Sm Eu Gd(NO3)3 Tb Dy Ho Er Tm Yb Lu
Ac Th Pa UO2(NO3)2 Np Pu Am Cm Bk Cf Es Fm Md No Lr