Hypofluorous acid

Hypofluorous acid

Hypofluorous acid Gas-phase structure
Hypofluorous acid
Names
IUPAC name Hypofluorous acid
Other names Hydrogen hypofluorite Hydrogen fluorate(I) Fluoric(-I) acid Hydrogen monofluoroxygenate(0)
Identifiers
CAS Number	14034-79-8 Y
ChemSpider	109936 N
Jmol 3D model	Interactive image
PubChem	123334
InChI InChI=1S/FHO/c1-2/h2H N Key: AQYSYJUIMQTRMV-UHFFFAOYSA-N N InChI=1/FHO/c1-2/h2H Key: AQYSYJUIMQTRMV-UHFFFAOYAN
SMILES OF
Properties
Chemical formula	HOF
Molar mass	36.0057 g mol−1
Appearance	pale yellow liquid above −117 °C white solid below −117 °C
Melting point	−117 °C (−179 °F; 156 K)
Boiling point	< 0 °C decomposes at 0 °C
Structure
Point group	Cs
Vapor pressure	{{{value}}}
Related compounds
Other cations	lithium hypofluorite, LiOF
Related compounds	hypochlorous acid, HOCl
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)
Infobox references

Hypofluorous acid is the chemical compound with the formula HOF. It is an intermediate in the oxidation of water by fluorine, which produces hydrogen fluoride and oxygen. It is the only hypohalous acid that can be isolated as a solid. HOF is explosive, decomposing to oxygen and HF. It was isolated in the pure form by fluorination of ice.

The compound has been characterized in the solid phase by X-ray crystallography as a bent molecule with an angle of 101°. The O–F and O–H bond lengths are 144.2 and 96.4 picometres, respectively. The solid framework consists of chains with O–H---O linkages. The structure has also been analyzed in the gas phase, a state in which the H—O—F bond angle is slightly narrower (97.2°).

For fluorine, the only known oxoacid is hypofluorous acid, HOF. It can be made by passing F₂ gas over ice at −40 °C, collecting the HOF gas, and condensing it:

F₂ + H₂O → HOF + HF

It decomposes explosively at room temperature to form HF and O₂:

2 HOF → 2 HF + O₂

Hypofluorous acid in acetonitrile (generated in situ by passing gaseous fluorine through "wet" acetonitrile) serves as a highly electrophilic oxygen-transfer agent. Treating phenanthroline with this reagent yielded the previously elusive 1,10-phenanthroline dioxide, more than 50 years after the first unsuccessful attempt.

This molecule is not very symmetric since the atoms are all different. It only has two symmetry operations: identity (E) and a mirror plane that goes through the three atoms. The assigned point group is Cs.

Hypofluorites

Hypofluorites are derivatives of OF⁻, which is the conjugate base of hypofluorous acid. One example is trifluoromethyl hypofluorite (CF₃OF).

See also

• Hypochlorous acid, a related compound that is more technologically important but has not been obtained in pure form.