Methanediol
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| Names | |||
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| IUPAC name
Methanediol[1]
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Other names
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| Identifiers | |||
463-57-0  |
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| Abbreviations | MADOL | ||
| 1730798 | |||
| ChEBI | CHEBI:48397 |
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| ChemSpider | 71348 |
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| EC Number | 207-339-5 | ||
| Jmol 3D model | Interactive image | ||
| PubChem | 79015 | ||
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| Properties | |||
| CH4O2 | |||
| Molar mass | 48.04 g·mol−1 | ||
| Appearance | Colourless liquid | ||
| Density | 1.199 g cm−3 | ||
| Boiling point | 194 °C (381 °F; 467 K) at 101 kPa | ||
| Vapor pressure | 16.1 Pa | ||
| Acidity (pKa) | 13.29[2] | ||
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Refractive index (nD)
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1.401 | ||
| Vapor pressure | {{{value}}} | ||
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Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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| Infobox references | |||
Methanediol, also known as formaldehyde monohydrate or methylene glycol, is an organic compound with chemical formula CH2(OH)2. It is the simplest geminal diol, and formally the second simplest carbohydrate (after formaldehyde).
Methanediol is a product of the hydration of formaldehyde H2C=O, and predominates in water solution: the equilibrium constant being about 103,[3] and in a 5% by weight solution of formaldehyde in water, 80% is in the methanediol form.
The compound is of some relevance to astrochemistry.[4]
Methanediol is listed as one of the main ingredients of "Brazilian blowout", a hair-straightening formula marketed in the US. The equilibrium with formaldehyde may cause some concern as formaldehyde in hair straighteners is a health hazard.[5]
See also
- Orthoformic acid (methanetriol)
- Orthocarbonic acid (methanetetraol)
References
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- ↑ Eric V. Anslyn, Dennis A. Dougherty (2006), Modern physical organic chemistry. University Science Books. ISBN 1-891389-31-9. 1095 pages
- ↑ A theoretical study of the conversion of gas phase methanediol to formaldehyde Kent DR, Widicus SL, Blake GA, Goddard WA The Journal of Chemical Physics -- September 8, 2003 -- Volume 119, Issue 10, pp. 5117-5120 doi:10.1063/1.1596392
- ↑ https://www.osha.gov/SLTC/formaldehyde/hazard_alert.html
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