Roussin's black salt
| 240 px | |
| 264 px | |
| Names | |
|---|---|
| Other names
Sodium heptanitrosyltri-μ3-thiotetraferrate
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| Identifiers | |
| 12518-87-5 | |
| Properties | |
| Fe4N7NaO7S3 | |
| Molar mass | 552.67 g/mol |
| Appearance | Black needles |
| Melting point | 198 to 200 °C (388 to 392 °F; 471 to 473 K) |
| Vapor pressure | {{{value}}} |
| Related compounds | |
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Related
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Roussin's Red Salt |
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Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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| Infobox references | |
Roussin's black salt is a chemical compound with the formula NaFe4S3(NO)7 first described by Zacharie Roussin.[1] It consists of the sodium salt of the [Fe4S3(NO)7]− anion and is classified as metal nitrosyl compound. The cluster anion has the geometry of an incomplete cubane with C3v symmetry. The dark colour of the complex is attributed to a number of charge-transfer interactions.[2]
Contents
Synthesis
Roussin’s Black Salt is produced by the reaction of nitrous acid, potassium hydroxide, potassium sulfide, and iron(II) sulfate in aqueous solution.[3] It can also be formed by the conversion of Roussin's Red Salt in mildly acidic conditions. This reaction is reversible and Roussin’s Red Salt is reformed upon alkalization of the reaction solution.
Uses
Roussin’s Black Salt is a nitric oxide donor. The nitric oxide donated by Roussin’s Black Salt has proven to be toxic to some melanoma cancer cells.[4] Also, Roussin’s Black Salt exhibits antibacterial activity in some food processing applications.[5]
See also
References
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