Sodium-cooled fast reactor

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Pool type sodium-cooled fast reactor (SFR)

The sodium-cooled fast reactor (SFR) is a Generation IV reactor project to design an advanced fast neutron reactor.

It builds on two closely related existing projects, the LMFBR and the Integral Fast Reactor, with the objective of producing a fast-spectrum, sodium-cooled reactor.

The reactors are intended for use in nuclear power plants to produce nuclear power from nuclear fuel.

Fuel cycle

The nuclear fuel cycle employs a full actinide recycle with two major options: One is an intermediate-size (150–600 MWe) sodium-cooled reactor with uranium-plutonium-minor-actinide-zirconium metal alloy fuel, supported by a fuel cycle based on pyrometallurgical reprocessing in facilities integrated with the reactor. The second is a medium to large (500–1,500 MWe) sodium-cooled reactor with mixed uranium-plutonium oxide fuel, supported by a fuel cycle based upon advanced aqueous processing at a central location serving a number of reactors. The outlet temperature is approximately 510–550 degrees Celsius for both.

Sodium as a coolant

Liquid metallic sodium may be used as the sole coolant, carrying heat from the core. Sodium has only one stable isotope, sodium-23. Sodium-23 is a very weak absorber of neutrons. When it does absorb a neutron it produces sodium-24, which has a half-life of 15 hours and decays in to magnesium-24.

Advantages

Schematic diagram showing the difference between the Loop and Pool designs of a liquid metal fast breeder reactor

An advantage of liquid metal coolants is that despite low specific heat, sodium melts at 371K and boils / vaporizes at 1156K, allowing a total "temperature outlier" range of 785K of heat variation between solid / frozen and gas / vapor states allowing the absorption of significant heat, less safety margins, in liquid phase. The high thermal conductivity properties effectively create a reservoir of heat capacity which provides thermal inertia against overheating.[1] Water is difficult to use as a coolant for a fast reactor because water acts as a neutron moderator that slows the fast neutrons into thermal neutrons. Unlike liquid sodium, water has a higher specific heat, with a smaller liquid range of just 100K between ice and gas at normal, sea-level atmospheric pressure conditions. While it may be possible to use supercritical water as a coolant in a fast reactor, this would require a very high pressure. In contrast, sodium atoms are much heavier than both the oxygen and hydrogen atoms found in water, and therefore the neutrons lose less energy in collisions with sodium atoms. Sodium also need not be pressurized since its boiling point is much higher than the reactor's operating temperature, and sodium does not corrode steel reactor parts.[1] The high temperatures reached by the coolant (up to 1156K for pure molten sodium, less all Generation IV margins of alarm call safety) permit a higher thermodynamic efficiency than in water cooled reactors.[2] The molten sodium, being electrically conductive, can be pumped by electromagnetic pumps.[2]

Disadvantages

A disadvantage of sodium is its chemical reactivity, which requires special precautions to prevent and suppress fires. If sodium comes into contact with water it explodes, and it burns when in contact with air. This was the case at the Monju Nuclear Power Plant in a 1995 accident. In addition, neutrons cause it to become radioactive; however, activated sodium has a half-life of only 15 hours.[1]

Design goals

The operating temperature should not exceed the melting temperature of the fuel. Fuel-to-cladding chemical interaction (FCCI) has to be designed against. FCCI is eutectic melting between the fuel and the cladding; uranium, plutonium, and lanthanum (a fission product) inter-diffuse with the iron of the cladding. The alloy that forms has a low eutectic melting temperature. FCCI causes the cladding to reduce in strength and could eventually rupture. The amount of transuranic transmutation is limited by the production of plutonium from uranium. A design work-around has been proposed to have an inert matrix. Magnesium oxide has been proposed as the inert matrix. Magnesium oxide has an entire order of magnitude smaller probability of interacting with neutrons (thermal and fast) than elements like iron.[3]

Actinides and fission products by half-life
Actinides[4] by decay chain Half-life
range (y)
Fission products of 235U by yield[5]
4n 4n+1 4n+2 4n+3
4.5–7% 0.04–1.25% <0.001%
228Ra 4–6 155Euþ
244Cm 241Puƒ 250Cf 227Ac 10–29 90Sr 85Kr 113mCdþ
232Uƒ 238Pu 243Cmƒ 29–97 137Cs 151Smþ 121mSn
248Bk[6] 249Cfƒ 242mAmƒ 141–351

No fission products
have a half-life
in the range of
100–210 k years ...

241Amƒ 251Cfƒ[7] 430–900
226Ra 247Bk 1.3 k – 1.6 k
240Pu 229Th 246Cm 243Amƒ 4.7 k – 7.4 k
245Cmƒ 250Cm 8.3 k – 8.5 k
239Puƒ№ 24.1 k
230Th 231Pa 32 k – 76 k
236Npƒ 233Uƒ№ 234U 150 k – 250 k 99Tc 126Sn
248Cm 242Pu 327 k – 375 k 79Se
1.53 M 93Zr
237Np 2.1 M – 6.5 M 135Cs 107Pd
236U 247Cmƒ 15 M – 24 M 129I
244Pu 80 M

... nor beyond 15.7 M years[8]

232Th 238U 235Uƒ№ 0.7 G – 14.1 G

Legend for superscript symbols
₡  has thermal neutron capture cross section in the range of 8–50 barns
ƒ  fissile
metastable isomer
№  naturally occurring radioactive material (NORM)
þ  neutron poison (thermal neutron capture cross section greater than 3k barns)
†  range 4–97 y: Medium-lived fission product
‡  over 200,000 y: Long-lived fission product

The SFR is designed for management of high-level wastes and, in particular, management of plutonium and other actinides. Important safety features of the system include a long thermal response time, a large margin to coolant boiling, a primary system that operates near atmospheric pressure, and intermediate sodium system between the radioactive sodium in the primary system and the water and steam in the power plant. With innovations to reduce capital cost, such as making a modular design, removing a primary loop, integrating the pump and intermediate heat exchanger, or simply find better materials for construction, the SFR can be a viable technology for electricity generation.[9]

The SFR's fast spectrum also makes it possible to use available fissile and fertile materials (including depleted uranium) considerably more efficiently than thermal spectrum reactors with once-through fuel cycles.

Reactors

Sodium-cooled reactors have included:

Most of these were experimental plants, which are no longer operational

Related:

See also

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References

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  2. 2.0 2.1 Lua error in package.lua at line 80: module 'strict' not found.
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  4. Plus radium (element 88). While actually a sub-actinide, it immediately precedes actinium (89) and follows a three-element gap of instability after polonium (84) where no isotopes have half-lives of at least four years (the longest-lived isotope in the gap is radon-222 with a half life of less than four days). Radium's longest lived isotope, at 1,600 years, thus merits the element's inclusion here.
  5. Specifically from thermal neutron fission of U-235, e.g. in a typical nuclear reactor.
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    "The isotopic analyses disclosed a species of mass 248 in constant abundance in three samples analysed over a period of about 10 months. This was ascribed to an isomer of Bk248 with a half-life greater than 9 y. No growth of Cf248 was detected, and a lower limit for the β half-life can be set at about 104 y. No alpha activity attributable to the new isomer has been detected; the alpha half-life is probably greater than 300 y."
  7. This is the heaviest isotope with a half-life of at least four years before the "Sea of Instability".
  8. Excluding those "classically stable" isotopes with half-lives significantly in excess of 232Th; e.g., while 113mCd has a half-life of only fourteen years, that of 113Cd is nearly eight quadrillion years.
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External links