Hardystonite

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Hardystonite
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Hardystonite is fluorescing blue in this Franklin Furnace specimen. Red is calcite, and green is willemite (size: 7.0 x 6.0 x 3.2 cm)
General
Category Sorosilicates
Formula
(repeating unit)
Ca2ZnSi2O7
Strunz classification 09.BB.10
Dana classification 55.4.2.2
Crystal symmetry Tetragonal 4 2m scalenohedral
Unit cell a = 7.8287(16) Å, c = 5.0140(2) Å; Z = 2
Identification
Color light brownish white, pale greyish-white, very pale pink
Crystal habit Massive granular
Crystal system Tetragonal
Cleavage [001] good, [100] and [110] fair
Tenacity Brittle
Mohs scale hardness 3-4
Luster vitreous, resinous, greasy, dull
Diaphaneity Transparent to translucent
Specific gravity 3.396–3.443
Optical properties Uniaxial (-)
Refractive index nω = 1.672 nε = 1.661
Ultraviolet fluorescence purple to violet blue in short wave ultraviolet light
Alters to hydrothermal alteration to clinohedrite
References [1][2][3]

Hardystonite is a rare calcium zinc silicate mineral first described from the Franklin, New Jersey, USA zinc deposits.[1] It often contains lead, which was detrimental to the zinc smelting process, so it was not a useful ore mineral.[4] Like many of the famous Franklin minerals, hardystonite responds to short wave ultraviolet (254 nm wavelength) light, emitting a fluorescence from dark purple to bright violet blue. In daylight, it is white to gray to light pink in color, sometimes with a vitreous or greasy luster. It is very rarely found as well formed crystals, and these are usually rectangular in appearance and rock-locked.[5]

File:Hardystonite-Clinohedrite-Calcite-170572.jpg
Hardystonite in plane light, same sample as in fluorescent light image above right

Hardystonite has a chemical composition of Ca2ZnSi2O7. It is frequently found with willemite (fluoresces green), calcite (fluoresces red), and clinohedrite (fluoresces orange). Hardystonite can be found altered to clinohedrite CaZn(SiO4)·H2O through direct hydrothermal alteration.[5] Other minerals often associated with hardystonite are franklinite, diopside, andradite garnet, and esperite (fluoresces yellow).

It was first described in 1899 by J.E. Wolff, when the New Jersey Zinc Company mines were located in what was called Franklin Furnace, in Hardyston Township, New Jersey.[5]

References

  1. 1.0 1.1 http://www.mindat.org/min-1818.html Mindat
  2. http://www.webmineral.com/data/Hardystonite.shtml Webmineral data
  3. Handbook of Mineralogy
  4. http://simplethinking.com/palache/hardystonite.stm Palache, Charles. The Minerals of Franklin and Sterling Hill, Sussex County, New Jersey. USGS Professional Paper 180, 1935.
  5. 5.0 5.1 5.2 http://franklin-sterlinghill.com/dunn/ch16/hardystonite.stm Dunn, Pete J. Franklin and Sterling Hill, New Jersey: the world's most magnificent mineral deposits. Dr. Pete J. Dunn, 2004.